Study of the Use of Activated Carbon Prepared from the Eichhornia Crassipes Plant for Removing Paracetamol from Aqueous Solutions

محتوى المقالة الرئيسي

Salwa H. Ahmed
Aisha Abd Al-Razaq Taha

الملخص

This study utilized activated carbon derived from Eichhornia crassipes (EC), a cheap plant that grows widely along riverbanks. The plant has fibrous roots and a taproot. It has thin, round, erect, wavy, smooth, and shiny leaves. The flowers are beautiful violet with six petals, and the fruits contain about 300 seeds each. The seeds can remain active for about 20 years. It negative impacts contain environment because it consumes large amounts of water, as a biosorbent in batch adsorption experiments for the removal of paracetamol from synthetic aqueous solutions. It was tested as an adsorbent for heavy metals, dyes, and other pollutants. The biosorbent was characterized using XRD, FTIR, BET, and SEM techniques. Several factors affecting the adsorption were considered in the study, including the adsorbent dosage (AC/NOH) (0.2-2.5 g/L), pH value (3-10), initial paracetamol concentration (10-80 mg/L), and contact duration (15-240 min). The highest removal efficiency of 75% for paracetamol was observed at a contact time of 180 min, pH value of 3, adsorbent dosage of 2 g, and initial paracetamol concentration of 10 mg/L at 25 °C, and the maximum adsorption capacity of 17.42 mg/g was observed with an R² value of 0.9851 on the Langmuir curve, while the pseudo-second order kinetic model provided a better fit with R² = 0.9987. The study utilizes Eichhornia Crassipes as a low-cost and environmentally friendly bio sorbent, which has not been explored in previous research on removing pharmaceutical contaminants. This result suggests its potential application in removing other pharmaceutical contaminants from aqueous solutions.

تفاصيل المقالة

القسم

Articles

المراجع

Oh WD, Chang VW, Lim TT. A Comprehensive Performance Evaluation of Heterogeneous Bi2Fe4O9/Peroxymonosulfate System for Sulfamethoxazole Degradation. Environmental Science and Pollution Research 2017; 26: 1026–1035.

Abed MF, Zarraq GA, Ahmed SH. Assessment of Groundwater Pollution Using Aqueous Geo-Environmental Indices, Baiji Province, Salah Al-Din, Iraq. Iraqi Geological Journal 2022; 55(1): 94–104.

Ahmed SH, Abed MF, Sharif SFA, Ibrahim AK. Appraising the Eco-Health of Tigris River Water Using Pollution Indicators and the Health Risk Assessment Model. Water Practice and Technology 2024; 19(7): 2839–2849.

Ahmed SH, Ibrahim AK, Abed MF. Assessing the Quality of the Groundwater and the Nitrate Exposure, North Salah Al-Din Governorate, Iraq: Quality of Groundwater. Tikrit Journal of Engineering Sciences 2023; 30(1): 25–36.

Abed MF, Zarraq GA, Ahmed SH. Hydrogeochemical Assessment of Groundwater Quality and Its Suitability for Irrigation and Domestic Purposes in Rural Areas, North of Baiji City-Iraq. Iraqi Journal of Science 2021; 62(7): 2296–2306.

Igwegbe CA, Aniagor CO, Oba SN, et al. Environmental Protection by the Adsorptive Elimination of Acetaminophen from Water: A Comprehensive Review. Journal of Industrial and Engineering Chemistry 2021; 104: 117–135.

Ahmed SH, Al-Jubouri SM, Zouli N, et al. Performance Evaluation of Polyethersulfone Membranes for Competitive Removal of Cd2+, Co2+, and Pb2+ Ions from Simulated Groundwater. Geofluids 2021; 2021: 1-11.

Mohammed HA, Khaleefa SA, Basheer MI. Photolysis of Methylene Blue Dye Using an Advanced Oxidation Process (Ultraviolet Light and Hydrogen Peroxide). Journal of Engineering and Sustainable Development 2021; 25(1): 59–67.

Ahmed SH, Rasheed EA, Rasheed LA, Abdulrahim FR. Decolorization of Cationic Dye from Aqueous Solution by Multiwalled Carbon Nanotubes. Journal of Ecological Engineering 2024; 25(2): 72–84.

Babel S, Kurniawan TA. Low-Cost Adsorbents for Heavy Metals Uptake from Contaminated Water: A Review. Journal of Hazardous Materials 2003; 97(1-3): 219–243.

Jung C, Son A, Her N, et al. Removal of Endocrine Disrupting Compounds, Pharmaceuticals, and Personal Care Products in Water Using Carbon Nanotubes: A Review. Journal of Industrial and Engineering Chemistry 2015; 27: 1–11.

Ahmed SH. Cu II Removal from Industrial Wastewater Using Low-Cost Adsorbent. Tikrit Journal of Engineering Sciences 2017; 24(2): 44–50.

Ibrahim AK, Ahmed SH, Abduljabbar RA. Adsorption of Congo Red Dye from Aqueous Solutions Using an Eco-Friendly Adsorbent Derived from Buckthorn Fruits. Tikrit Journal of Engineering Sciences 2024; 31(1): 182–192.

Ibrahim AK, Ahmed SH, Abduljabbar RA. Removal of Methylene Blue Dye from Aqueous Solutions Using Cordia Myxa Fruits as a Low-Cost Adsorbent. Tikrit Journal of Engineering Sciences 2023; 30(3): 90–99.

Sajid M, Bari S, Rehman MSU, et al. Adsorption Characteristics of Paracetamol Removal onto Activated Carbon Prepared from Cannabis sativum Hemp. Alexandria Engineering Journal 2022; 61(9): 7203–7212.

Abdulrahim FR. Evaluation of Activated Carbon from Cordia Myxa Used as an Adsorbent for Pharmaceutical Removal from Wastewater. Ondokuz Mayis University Institute of Graduate Studies 2022.

Al-Ma’abreh AM, Edris G, Haddad MK. Sonicating for the Uptake of Paracetamol from Solution by Activated Carbon from Oak: Kinetics, Thermodynamics, and Isotherms. Adsorption Science and Technology 2023; 2023: 9922446.

Akça İK, Köklü R. Removal of Paracetamol by Powdered Activated Carbon Synthesized from Orange Peels. Sakarya University Journal of Science 2023; 27(1): 168–180.

Lima HDP, Asencios YJ. Eichhornia crassipes (Mart.) Solms (Natural or Carbonized) as Biosorbent to Remove Pollutants in Water. SN Applied Sciences 2021; 3: 1–18.

Chowdhury P, Sajid M, Jahan N, et al. A Secondary Approach with Conventional Medicines and Supplements to Recuperate Current COVID-19 Status. Biomedicine and Pharmacotherapy 2021; 142: 111956.

Nourmoradi H, Moghadam KF, Jafari A, Kamarehie B. Removal of Acetaminophen and Ibuprofen from Aqueous Solutions by Activated Carbon Derived from Quercus Brantii (Oak) Acorn as a Low-Cost Biosorbent. Journal of Environmental Chemical Engineering 2018; 6: 6807–6815.

Ali HQ, Mohammed AA. Elimination of Congo Red Dyes from Aqueous Solution Using Eichhornia Crassipes. Iraqi Journal of Chemical and Petroleum Engineering 2020; 21(4): 21–32.

Dada AO, Olalekan AP, Olatunya AM, et al. Temkin and Dubinin–Radushkevich Isotherms Studies of Equilibrium Sorption of Zn2+ into Phosphoric Acid Modified Rice Husk. IOSR Journal of Applied Chemistry 2012; 3(1): 38–45.

Ayawei N, Ebelegi AN, Wankasi D. Modelling and Interpretation of Adsorption Isotherms. Journal of Chemistry 2017; 2017: 3039817.

Anitha T, Senthil Kumar P, Sathish Kumar K. Binding of Zn (II) Ions to Chitosan–PVA Blend in Aqueous Environment: Adsorption Kinetics and Equilibrium Studies. Environmental Progress and Sustainable Energy 2015; 34(1): 15–22.

Foo K, Hameed B. Insights into the Modeling of Adsorption Isotherm Systems. Journal of Chemical Engineering 2010; 156(1): 2–10.

Natarajan R, Banerjee K, Kumar PS, et al. Performance Study on Adsorptive Removal of Acetaminophen from Wastewater Using Silica Microspheres: Kinetic and Isotherm Studies. Chemosphere 2021; 272: 129896.

Kumar PS, Ramalingam S, Kirupha SD, et al. Adsorption Behavior of Nickel (II) onto Cashew Nut Shell: Equilibrium, Thermodynamics, Kinetics, Mechanism and Process Design. Chemical Engineering Journal 2011; 167(1): 122–131.

Moussavi G, Hossaini Z, Pourakbar M. High-Rate Adsorption of Acetaminophen from the Contaminated Water onto Double-Oxidized Graphene Oxide. Chemical Engineering Journal 2016; 287: 665–673.

Can M, Bulut E, Örnek A, Özacar M. Synthesis and Characterization of Valonea Tannin Resin and Its Interaction with Palladium (II), Rhodium (III) Chloro Complexes. Chemical Engineering Journal 2013; 221: 146–158.

Fito J, Tibebu S, Nkambule TT. Optimization of Cr (VI) Removal from Aqueous Solution with Activated Carbon Derived from Eichhornia Crassipes Under Response Surface Methodology. BMC Chemistry 2023; 17(1): 4.

Tessema TS, Adugna AT, Kamaraj M. Removal of Pb (II) from Synthetic Solution and Paint Industry Wastewater Using Activated Carbon Derived from African Arrowroot (Canna indica) Stem. Advances in Materials Science and Engineering 2020; 2020: 8857451.

Najmudeen TM, Arakkal Febna MA, Rojith G, Zacharia PU. Characterisation of Biochar from Water Hyacinth Eichhornia crassipes and the Effects of Biochar on the Growth of Fish and Paddy in Integrated Culture Systems. Journal of Coastal Research 2019; 86: 225–234.

Özer ET. Removal of Amoxicillin from Aqueous Solutions with Activated Carbon: Kinetic and Equilibrium Studies. European Journal of Science and Technology 2020; 18: 833–839.

Wong S, Lim Y, Ngadi N, et al. Removal of Acetaminophen by Activated Carbon Synthesized from Spent Tea Leaves: Equilibrium, Kinetics and Thermodynamics Studies. Powder Technology 2018; 338: 878–886.

Nguyen DT, Tran HN, Juang RS, et al. Adsorption Process and Mechanism of Acetaminophen onto Commercial Activated Carbon. Journal of Environmental Chemical Engineering 2020; 8(6): 104408.

Lee WJ, Goh PS, Lau WJ, Ismail AF. Removal of Pharmaceutical Contaminants from Aqueous Medium: A State-of-the-Art Review Based on Paracetamol. Arabian Journal for Science and Engineering 2020; 45: 7109–7135.

Joshiba GJ, Kumar PS, Christopher FC, et al. Fabrication of Novel Amine-Functionalized Magnetic Silica Nanoparticles for Toxic Metals: Kinetic and Isotherm Modeling. Environmental Science and Pollution Research 2020; 27: 27202–27210.

Nandi BK, Goswami A, Purkait MK. Adsorption Characteristics of Brilliant Green Dye on Kaolin. Journal of Hazardous Materials 2009; 161(1): 387–395.

Neeraj G, Krishnan S, Kumar PS, et al. Performance Study on Sequestration of Copper Ions from Contaminated Water Using Newly Synthesized High Effective Chitosan Coated Magnetic Nanoparticles. Journal of Molecular Liquids 2016; 214: 335–346.

Mukoko T, Mupa M, Guyo U, Dziike F. Preparation of Rice Hull Activated Carbon for the Removal of Selected Pharmaceutical Waste Compounds in Hospital Effluent. Water, Air, and Soil Pollution 2015; 226: 2148.

Weng CH, Lin YT, Tzeng TW. Removal of Methylene Blue from Aqueous Solution by Adsorption onto Pineapple Leaf Powder. Journal of Hazardous Materials 2009; 170(1): 417–424.

Zahoor M. Effect of Agitation Speed on Adsorption of Imidacloprid on Activated Carbon. Journal of the Chemical Society of Pakistan 2011; 33(6): 305.

Villaescusa I, Fiol N, Poch J, et al. Mechanism of Paracetamol Removal by Vegetable Wastes: The Contribution of π–π Interactions, Hydrogen Bonding and Hydrophobic Effect. Desalination 2011; 270(1-3): 135–142.

Rahman N, Nasir M. Effective removal of Acetaminophen from Aqueous Solution Using Ca (II)-Doped Chitosan/β-Cyclodextrin Composite. Journal of Molecular Liquids 2020; 301: 112454.

المؤلفات المشابهة

يمكنك أيضاً إبدأ بحثاً متقدماً عن المشابهات لهذا المؤلَّف.