Mathematical Modeling of the Instantaneous Reaction of H2S Mea in a Falling Film Reactor
Main Article Content
Abstract
A mathematical model was formulated using the absorption of carbon dioxide by monoethanolamine amine as an absorbent in a falling film reactor. A program wrote in Fortran language was used to obtain these profiles via using of multi grid method through programming of kinetic and thermodynamic equation and physical properties of the studied system. Through the formulated model film thickness, surface temperature, velocity, concentration and temperature profiles were obtained. The mathematical analysis validated by a test run in a Baiji refinery through intrusion of liquid flow rate, liquid concentration and gas fraction. In this study we have four factors as independent variables ,they are mole fraction of hydrogen sulfide in gaseous mixture (Y) (0.05, 0.75 and 0.1), molar concentration of absorbent (monoethanolamine) (CMEA) (0.05, 0.075 and 1 M), volumetric flow rate of liquor MEA (QMEA) (5, 10, 15, and 20), and its temperature (T) (30, 35, 40, 45, 50 and 55 C).
Article Details
Section

This work is licensed under a Creative Commons Attribution 4.0 International License.
THIS IS AN OPEN ACCESS ARTICLE UNDER THE CC BY LICENSE http://creativecommons.org/licenses/by/4.0/
References
Glenn Shiveler , Sulzer Chemtech and Sixtos Solis, “Retrofit of a H2S Selective Amine Absorber Using MellapakPlus Structured Packing”, Spring AIChE Meeting, 2005.
Akanksha Chaudhary, K.K. Pant, and K. Srivastava. Chemical Engineering Department, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, India, 2005.
Johnson, G.R. & Crynes, B.L., Ind. Eng. Chem., Process Des. Develop.13 ,1974, 6-14.
Davis, E.J., Ouwerkerk, M.V. & Venkatesh, S., Chem Eng. Sci. 34 (1979) 539-550.
Mann, R. & Moyes, H., AIChE J. 23 (1977) 17-23.
Gutierrez, J., Mans, C. & Costa, J., Ind. Eng. Chem. Res. 27 (1988) 1701-1707.
Dabir, B., Riazi, M.R. & Davoudirad, H.R., Chem. Eng. Sci. 51 (1996) 2553-2558.
Bhattacharya, A., Gholap, R.V. & Chaudhari, R.V.,Canadian J. Chem. Eng. 66 (1988) 599-604.
Nielsen, P.H. & Villadsen, J., Chem. Eng. Sci., 38 ,1983, 1439- 1454.
R. Riazi & A. Faghri, AIChE J. 31 (12) (1985) 1967-1972.
Jian-Gang Lua, You-Fei Zheng, a, and Du-Liang He, Separation and Purification Technology, 52, December 2006, 209-217.
P. Mandala and S.S. Bandyopadhyay, Chemical Engineering Science, 60, November 2005, 6438-6451.
Kreulen, C.A. Smolders, G.F. Versteeg and W.P.M. Swaaij, Journal of Membrane Science, 82, July 1993, 185-197.
Kreulen, G. F. Versteeg, C. A. Smolders and W. P. M. Van Swaaij, Journal of Membrane Science, 73, October 1992, 293- 304.
Wei-Chung Yu and Gianni Astarita, Chemical Engineering Science , 42, 1987, 419-424.
J.G. Huttenhuisa, , N.J. Agrawala, J.A. Hogendoornb and G.F. Versteeg, Journal of Petroleum Science and Engineering 55, January 2007, 122-134.
Bird R., Steward W., and Lightfoot E., “Transport phenomena”, Wiley, New York, 1960.
Hanratty T., and JM. Engen, AIChE J., 3, P.299, 1957
Cohen L. and Hanartty T. , AIChE J., 11, P.138, 1965.
Coulson J. and Richardson J., “Chemical Engineering”, Vol.1, 3rd Edition, Pergamon Press,England, 1983.
Dankwerts, P.V., Chem. Eng. Sci., 34, P.443, 1979.
Bendall J. Pitipanapong, eparation and Purification Technology ,52 ,2007, 416 422.
Astarita G., Chem., Eng. Sci., 16, P.202, 1961.
Wilke , C.R., J. Chem. Phys., 18: 517, 1950.